Controlled Radical Polymerization by Krzysztof Matyjaszewski (Eds.)

By Krzysztof Matyjaszewski (Eds.)

content material: basics of controlled/living radical polymerization / Krzysztof Matyjaszewski --
Radical addition to alkenes : a theoretical viewpoint / Leo Radom, Ming Wah Wong, and Addy Pross --
components influencing the addition of radicals to alkenes / Anne Ghosez-Giese and Bernd Giese --
Cascade radical reactions in natural synthesis : an outline / Dennis P. Curran --
Selective product formation with organometallic radicals of nickel and zinc / Gerard van Koten, Robert A. Gossage, David M. Grove, and Johann T.B.H. Jastzebski --
Pulsed laser experiments directed towards the targeted learn of free-radical polymerizations / Sabine Beuermann and Michael Buback --
Termination fee coefficients from molecular weight distributions / Paul A. Clay, David I. Christie, and Robert G. Gilbert --
The size and which means of radical reactivity ratios / Johan P.A. Heuts, Michelle L. Coote, Thomas P. Davis, and Lloyd P.M. Johnston --
Electron spin resonance reviews of radical polymerization / Mikiharu Kamachi --
The sturdy free-radical polymerization procedure : position of extra nitroxide / M.K. Georges, R.P.N. Veregin, and okay. Daimon --
Mechanism and kinetics of nitroxide-controlled free-radical polymerization / Takeshi Fukuda, Atsushi Goto, Kohji Ohno, and Yoshinobu Tsujii --
Styrene polymerization mediated by means of 5-membered cyclic nitroxides / B. Yamada, Y. Miura, Y. Nobukane, and M. Aota --
Nitroxide-mediated radical polymerization : end-group research / Yucheng Zhu, I.Q. Li, B.A. Howell, and D.B. Priddy --
Controlled/living free-radical polymerization of styrene and n-butyl acrylate within the presence of a singular uneven nitroxyl radical / D. Benoit, S. Grimaldi, J.P. Finet, P. Tordo, M. Fontanille, and Y. Gnanou --
Nitroxide-mediated managed radical polymerization : towards keep watch over of molar mass / Stefan A.F. Bon, Frank A.C. Bergman, J.J.G. Steven van Es, Bert Klumperman, and Anton L. German --
Mechanistic facets of atom move radical polymerization / Krzysztof Matyjaszewski --
Atom move radical polymerization of methyl methacrylate : influence of phenols / D.M. Haddleton, A.J. Shooter, A.M. Heming, M.C. Crossman, D.J. Duncalf, and S.R. Morsley --
residing radical polymerization mediated by means of transition metals : fresh advances / Mitsuo Sawamoto and Masami Kamigaito --
keep watch over of radical polymerizations by means of metalloradicals / B.B. Wayland, S. Mukerjee, G. Poszmik, D.C. Woska, L. Basickes, A.A. Gridnev, M. Fryd, and S.D. Ittel --
Photochemical polymerizations initiated and mediated by way of soluble organocobalt compounds / Labros D. Arvanitopoulos, Michael P. Greuel, Brian M. King, Anne ok. Shim, and H. James Harwood --
Controlled-growth free-radical polymerization of methacrylate esters : reversible chain move as opposed to reversible termination / Graeme Moad, Albert G. Anderson, Frances Ercole, Charles H.J. Johnson, Julia Krstina, Catherine L. Moad, Ezio Rizzardo, Thomas H. Spurling, and San H. Thang --
Free-radical synthesis of practical polymers concerning addition-fragmentation reactions / P. Chaumont, D. Colombani, L. Boiteau, J.P. Lamps, M.-O. Zink, C.P.R. Nair, and D. Charmot --
purposes of Barton esters in polymer synthesis and amendment through free-radical methods / W.H. Daly and T.S. Evenson --
the right way to make polymer chains of assorted shapes, compositions, and functionalities via atom move radical polymerization / Scott G. Gaynor and Krzysztof Matyjaszewski --
managed radical polymerization tools for the synthesis of nonionic surfactants for CO2 / D.E. Betts, T. Johnson, D. LeRoux, and J.M. DeSimone --
layout options for branched and hugely branched macromolecular architectures utilizing nitroxide-mediated dwelling free-radical systems / Craig J. Hawker, Eva E. Malmström, Jean M.J. Fréchet, Marc R. Leduc, R. Bernard Grubbs, and George G. Barclay --
Stereochemical keep an eye on of free-radical polymerization of vinyl monomers / Tamaki Nakano and Yoshio Okamoto.

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Fischer, H. Helv. Chim. Acta 1995, 78, 194. Wu, J. ; Fischer, H. Int. J. Chem. , 1995, 27, 167. ; Fischer, H. J. Am. Chem. Soc. 1996, 118, 437. ; ACS Symposium Series; American Chemical Society: Washington, DC, 1998. ch003 Department of Chemistry, University of Basel, St. Johanns-Ring 19, CH-4056 Basel, Switzerland The addition of radicals to alkenes is largely governed by polar and steric effects as well as, in some cases, stability effects. These factors play also an important role on the regio- and the stereoselectivity of the additions and in radical polymerization reactions.

Phys. Org. Chem. 1995, 8, 197. , E d . Cationic Polymerizations: Mechanisms, Synthesis and Applications; Marcel Dekker: New York, 1996. ; Lin, C . - H . Makromol. Chem. Macromol. Symp. 1991, 47, 221. (8) Müller, A . H. E . ; Y a n , D . ; Litvinienko, G . Macromolecules 1995, 28, 4326. ; Müller, Α. H. E . Polym. Prepr. (Am. Chem. , Div. ) 1997, 38(1), 6. (10) G o l d , L. J. Chem. Phys. 1958, 28, 91. ; ACS Symposium Series; American Chemical Society: Washington, DC, 1998. Polym. 26 (11) Hawker, C.

Acknowledgments. Support from A R O , N S F , O N R , P R F and A T R P Consortium is gratefully acknowledged. References: (1) M o a d , G . ; Solomon, D. H. The Chemistry of Free Radical Polymerization; Pergamon: Oxford, 1995. (2) Webster, O. Science 1991, 251, 887. (3) Szwarc, M. Nature 1956, 176, 1168. ; Lee, B. Polym. Int. 1992, 27, 359. (5) Matyjaszewski, K. J. Phys. Org. Chem. 1995, 8, 197. , E d . Cationic Polymerizations: Mechanisms, Synthesis and Applications; Marcel Dekker: New York, 1996.

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